Systems and methods for producing and using fine particle materials

ABSTRACT

Systems and methods of making and using fine particle materials in pigment blends and for using the aforementioned pigment blends in paint, coating, or coloring compositions are provided. This invention further provides systems and methods of enhancing the visual appearance of a variety of substrates by introducing a paint, coating, or coloring composition to the substrate. The fine particle materials of the present invention have a substantially random geometric shape, a particle size less than about 100 microns, and help provide both functional and visual enhancing properties to compositions and substrates containing these fine particle materials.

CROSS REFERENCE TO RELATED APPLICATION

This application is a continuation of U.S. application Ser. No.09/607,447, filed Jun. 30, 2000, now U.S. Pat. No. 6,447,595, whichclaims the benefit of U.S. provisional patent application No.60/142,087, filed Jul. 2, 1999.

BACKGROUND OF THE INVENTION

The present invention relates to systems and methods for producing andusing fine particle materials. More particularly, the present inventionrelates to systems and methods for taking raw materials, pulverizingthose raw materials, and incorporating the pulverized materials intoproducts to enhance the visual appearance of the products.

In numerous commercial products, pigment blends are used to create colorand visual effects that aesthetically appeal to consumers. Becausedifferent consumers have different preferences to various visualeffects, a designer's ability to create and control these effects isoften important to the marketability of a product. Often, additives suchas coated mica flakes, metal flakes, and glass flakes have been used inpigment blends to enhance the visual appeal of items such asautomobiles, boats, planes, appliances, signs, painted surfaces,fabrics, and other consumer goods.

Depending on the nature of the substrate to which the pigment blend isintroduced, there are certain visual effects that often have strongaesthetic appeal to consumers. Coated mica flakes, for example, is oneof the more common additives used to improve luster and depth of colorof paint compositions on cars. Metal flakes, such as aluminum flakes,are another common additive used to improve the sparkle of paint andcoatings.

While the aforementioned additives offer some of the visual effects thattypically appeal to consumers, a need remains for an economical pigmentblend that enables a designer to create and control a broader range ofvisual effects. Moreover, a need always exists for improved ways toenhance the functional properties of paint and coating compositions,such as increased durability, increased travel, improved patterncontrol, UV screening, and reduced settling problems from particulatesin unapplied paint or coatings.

SUMMARY OF THE INVENTION

These and other needs are satisfied in accordance with the presentinvention by providing systems and methods for making and using fineparticle materials in pigment blends and for using the aforementionedpigment blends in paint, coating, or coloring compositions. Theinvention further provides systems and methods for enhancing the visualappearance of a variety of substrates by introducing such a paint,coating, or coloring composition to the substrate. The fine particlematerials of the present invention have a substantially random geometricshape, a particle size less than about 100 microns, and help provideboth functional and visual enhancing properties to compositions andsubstrates containing these fine particle materials.

The fine particle materials of the present invention may be madegenerally from any pulverizable material. Initially, solid rawpulverizable material may be sorted according to type and subsequentlycleaned of any impurities. Depending on the original size of the solidraw material, it may be sent, either before or after cleaning, to acrusher to reduce the size of the raw material into pieces suitable forefficient pulverizing. Once the raw material has been separated,crushed, and cleaned, it is conveyed to a first feed hopper that thenfeeds the raw material to a first pulverizer. The pulverized particlesmade by pulverizing the raw material may then be sent to a screenclassifier to remove any remaining impurities, such as particle metalwaste resulting from wear and tear of the innards of the pulverizer, ifnecessary. Next, the pulverized particle material is classifiedaccording to size. Pulverized particle materials that do not meet thedesired size limitation may be sent to be either pulverized again ormilled to further reduce the particle material to a size suitable forthe desired application. Alternatively, the pulverized material producedby the first pulverizer may be sent immediately to a ball mill to helpreduce the particle material to a desired particle size.

The fine particle materials of the present invention may be used inpigment blends to enhance the visual and functional properties of asubstrate. One or more coloring agents may be optionally added to thepigment to assist with enhancing the visual appearance of the substrateto be treated. The visual appearance of the substrate may be enhanced byintroducing a coating, coloring, or paint composition containing thepigment blend with the fine particle material to the substrate by eitherapplying the composition to the surface of the substrate or byincorporating the composition into the substrate itself.

BRIEF DESCRIPTION OF THE DRAWINGS

Further features of the invention, its nature and various advantageswill be more apparent from the following detailed description of thepreferred embodiments, taken in conjunction with the accompanyingdrawing, in which like reference characters refer to like partsthroughout, and in which:

FIGS. 1A-1C illustrate one embodiment of a system for producing fineparticle materials in accordance with the present invention.

FIG. 2 illustrates an alternative embodiment of a system for producingfine particle materials that uses a ball mill in conjunction with apulverizer in accordance with the present invention.

FIG. 3 illustrates a partially schematic and partially cut-away view ofan embodiment of a pulverizer suitable for use in accordance with thepresent invention.

FIG. 4 illustrates an enlarged, partially schematic and partiallycut-away view of one bearing assembly for the pulverizer of FIG. 3.

FIG. 5 illustrates an enlarged, partially schematic and partiallycut-away view of another bearing assembly for the pulverizer of FIG. 3.

FIG. 6 illustrates an enlarged, partially schematic and partiallycut-away view of yet another bearing assembly for the pulverizer of FIG.3.

FIG. 7 illustrates an enlarged, partially schematic and partiallycut-away view of still another bearing assembly for the pulverizer ofFIG. 3.

FIG. 8 illustrates a plan view of a preferred embodiment of a top ringfor the pulverizer of FIG. 3.

FIG. 9 illustrates a cross-sectional view of the ring of FIG. 8, takenalong the line 7—7 thereof.

FIG. 10 illustrates a cross-sectional view of the ring of FIG. 8, takenalong the line 8—8 thereof.

FIG. 11 illustrates a partially schematic plan view of a preferredembodiment of an impact ring of the pulverizer of FIG. 3.

FIG. 12 illustrates a cross section of the ring of FIG. 11, taken alongthe line 10—10 thereof.

FIG. 13 illustrates an enlarged fragment of the ring of FIG. 11 showinga preferred ridged and grooved inner surface.

FIGS. 14A-B illustrate alternate shafts that are split into two or moreportions and connected by torque transferring couplings for thepulverizer of FIG. 3.

FIG. 15 illustrates a schematic for additionally or alternativelycooling the shaft of the pulverizer of FIG. 3 to prevent expansion ofthe shaft.

FIG. 16 illustrates yet another shaft for the pulverizer of FIG. 3 thatincludes a threaded section enabling a user to adjust the gaps betweenthe vanes of impellers and baffles plates.

FIG. 17 illustrates an alternative embodiment of the pulverizer of FIG.3 incorporating additional vanes along the bottom of one or more of theimpellers.

FIGS. 18A-D show scanning-electron-microscope micrographs of mirrorizedglass chips produced in accordance with the present invention.

FIG. 19 shows a particle size distribution of fine particle glassproduced in accordance with the present invention.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

Turning to FIGS. 1A-1C, one embodiment of a system 100 for producingfine particle materials in accordance with the present invention isshown. As illustrated, system 100 is directed toward the production offine particle glass. However, it should be noted that with minormodification, system 100 could be used to produce other types of fineparticle materials, including rubber, oyster shell, rock minerals, coal,aluminum, and other similar crushable materials.

Initially raw material glass is stored in storage bins 102. Asillustrated in FIG. 1A, system 100 may contain six storage bins 102 orany suitable number of storage bins 102. Within storage bins 102, theraw material glass may be sorted by type. For example, the raw materialglass may be separated by type and color so that clear glass, greenglass, amber glass, aluminum-coated mirror, gold-coated mirror, andmixed glass are each stored in a different one of storage bins 102. Mostcommonly the mirrors will be silver-copper coated with a paint backing.In addition to using mirrors with different types of backing, mirrors ofvarying thickness may also be employed. For example, other raw materialproducts, such as one-quarter inch or one-half inch mirror may also beused. The one-quarter inch and one-half inch mirrors may be mixedtogether or treated separately to yield fine glass particles. Dependingon the application and visual effect sought, one or more classes ofmirrors may be combined to yield a combination of fine particlematerials that provide sought after visual enhancing properties.

Using conveyer 104, glass may be removed from any one or more of storagebins 102 and transported to magnetic separator 106. Magnetic separator106 may be used to remove any metal waste that may be mixed in with theraw glass. Conveyer 104 then carries the glass to crusher 108. Crusher108 is used to crush the raw material glass down into a size suitablefor further processing. The crushed glass is then conveyed towasher/dryer 110. In washer/dryer 110, the crushed glass is then removedof paper, glue, and any other impurities that may be present in thecrushed glass. In an alternative embodiment, the glass may be firstcleaned by washer/dryer 110 before it is crushed by crusher 108.Alternatively, as part of the cleaning process, the combustibleimpurities that may accompany the glass (e.g., labels from recycledglass) may be burned off of the raw glass material either before orafter the glass is crushed by crusher 108.

Once the glass has been crushed, washed and dried, the glass is thenconveyed by conveyer 112 to a first feed hopper 114. First feed hopper114 then feeds the crushed and cleaned glass to a first pulverizer 116by way of a screw conveyer. First pulverizer 116 performs an initialpass on the crushed glass and provides first-stage pulverized glassthrough pipe 118 to dust collector 120. Dust collector 120 releases airpressure from the output of first pulverizer 116. Attached to dustcollector 120 is a material transport system 122 that restabilizes theair pressure in the output of dust collector 120 and then drives thefirst-stage pulverized glass through pipe 124 to screen classifier 202as shown in FIG. 1B.

Once the screen classifier 202 receives the pulverized glass, it removesany remaining impurities, including any particle metal waste resultingfrom wear and tear of the innards of pulverizer 116 or 128. In somecases, the screen classifier may not be needed if removal of impuritiesis not required. The pulverized glass output from screen classifier 202then flows through pipe 204 to first air classifier 206. First airclassifier 206 then classifies the pulverized glass into three groups.The first group is the pulverized glass less than 5 microns in size.This glass is output through pipe 208. The second group is thepulverized glass between 5 and 15 microns. This glass is output throughpipe 210. The third group is the pulverized glass larger than 15microns. This glass is output through pipe 212 and passed to second airclassifier 213. Second air classifier 213 then also classifies the glassinto three groups. The first group is the glass less than 5 microns insize that managed to pass through to second classifier 213. This glassis output through pipe 208. The second group is the glass that isbetween 15 and 30 microns in size. This glass is output through pipe214. Finally the glass that is larger than 30 microns in size is outputas the third group through pipe 216 back to second feed hopper 126 asshown in FIG. 1A.

Once the first-stage pulverized glass that is greater than 30 microns insize has been sent to second feed hopper 126, the glass is thenrepulverized by second pulverizer 128 which provides second-stagepulverized glass through pipe 130 to dust collector 132. Dust collector132 releases air pressure from the output of second pulverizer 128.Attached to dust collector 132 is a material transport system 134 thatrestabilizes the air pressure in the output of dust collector 132 andthen drives the second-stage pulverized glass back through pipe 124 toscreen classifier 202 as shown in FIG. 1B. This second-stage pulverizedglass then repeats the processing at air classifiers 206 and 213 thatwas performed on the first-stage pulverized glass.

Finally, as shown in FIG. 1C, the less than 5 micron pulverized glass inpipe 208 is then passed to dust collector 302 which releases airpressure in pipe 208. Attached to dust collector 302 is a materialtransport system 304 that restabilizes the air pressure and then passesthe glass to group of silos 306 via pipe 305. Similarly, the 5 to 15micron glass in pipe 210 is passed to group of silos 308 and the 15 to30 micron glass in pipe 214 is passed to group of silos 310. Each of thesilos in groups 306, 308, and 310 may provide a silo for a particulartype of glass in one of storage bins 102.

In an alternative embodiment, as shown in FIG. 2, solid raw glassmaterial is sent to feed hopper 312 and pulverized by pulverizer 314.The first-stage pulverized particle material made by pulverizer 314 maybe further reduced in size by a ball mill 316 before it is classifiedaccording to particle size by air classifier 320. Particles that need tobe further reduced in size may be sent back to pulverizer 314 by returnpipe 318. Particles that have the desired particle size are output todust collector 322.

In a second alternative embodiment, a ball mill may be substituted inplace of second pulverizer 128 to help further reduce the particle sizeof the pulverized material. Depending on the particle size of thepulverized material, the ball mill may be a more efficient method ofreducing the pulverized material to a particle size less than 30microns. In particular, pulverized material between about 50 and 100microns in size is well suited for use with a ball mill to obtain fineparticle materials having a particle size less than about 30 microns. Incontrast, pulverized materials that are greater than 100 microns may bemore efficiently reduced in size by a pulverizer.

Alternative classification sizes may be used, if necessary, to suit theparticular application for which the pulverized material will be used.

System 100 may additionally include a soft-start regulator for producingcontrolled delivery of power to the pulverizers and a computer controlsystem for controlling and synchronizing the operation of the othercomponents of system 100.

Storage bins 102, conveyer 104, crusher 108, washer/dryer 110, conveyer112, feed hoppers 114, 126, and 312, dust collectors 120, 132, and 302,material transport systems 122, 134, and 304, screen classifier 202, airclassifiers 206, 213, and 320, groups of silos 306, 308, and 310, thesoft-start regulators, and the computer control system used in system100 may be any suitable components for use in the production of theparticular fine particle material desired. Also, one or more of thesecomponents may be omitted from system 100 and additional components maybe added to system 100, without departing from the spirit and scope ofthe invention.

For example, a glass tempering system could be incorporated into theflow of glass between storage bins 102 and groups of silos 306, 308, and310 in system 100. By tempering the glass, added benefits can berealized in the product in which the fine particle glass is used.Alternatively, a tempering process could be implemented in one of theexisting components of system 100 such as washer/dryer 110 orpulverizers 116 or 128.

An example of a pulverizer suitable for use as pulverizers 116, 128, 314in system 100 is described in Greco U.S. Pat. No. 5,820,044 (hereinafter“the '044 patent”) issued Oct. 13, 1998, which is hereby incorporated byreference herein in its entirety. As explained in the '044 patent, andshown in FIG. 3, solid material to be pulverized enters an inlet 11 to aprocessing chamber 12 within container 13. Chamber 12 is divided intofour compartments by baffle plates 14, and each compartment contains arotor 15. Rotors 15 are fixed to shaft 50 for rapid rotation withinprocessing chamber 12.

Each rotor 15 has peripheral vanes 16 that impel solid material radiallyoutward against inside surfaces of rings 20 that are arranged aroundeach impeller 15. Rings 20 preferably have multi-sided internal surfacessurrounding and confronting each respective impeller 15. Solid materialflung radially outward by vanes 16 on rotors 15 impacts against theinternal surfaces of rings 20 for breaking the solid material down intofiner particles.

As the particles become smaller, they move downward through successivestages within processing chamber 12. The particles pass through spacesthat are available between vanes 16 of impellers 15 and the insidesurfaces of rings 20. The material then flows through central openingsof successive baffle plates 14 to enter lower stages where it encounterssuccessive impellers 15.

The pulverized material outlet from the lowermost stage below thelowermost impeller 15 proceeds downward through an output chute 18. Therotation of vanes 16 on impellers 15 pumps air through processingchamber 12 along with solid material, and this helps force pulverizedparticles through output chute 18, along with an air stream.

Considerable power is input to shaft 50 via pulley 51, for violentlyhurling solid material outward against rings 20. In a working prototype,for example, a 300 horsepower motor drives shaft 50 by a toothed belt(not shown) mating with teeth on pulley 51. The power expended inprocessing chamber 12 produces considerable heat. The shaft 50 lengthensabout 3 mm from the heat generated during operation. The exactlengthening of shaft 50 will depend on materials used in construction,materials being processed, power input, and other variables; but howevermuch shaft lengthening actually occurs must be accounted for.

As shown in FIGS. 4-7, the shaft lengthening may be accommodated for bya floating bearing system. Turning to FIG. 4, beginning at the bottom,shaft 50 is supported by bottom bearing 30, as best shown in FIG. 4. Apair of ball bearings 31 and 32 are fitted to a lower region of shaft 50between bottom collars 33 and a top collar 34. Ball bearings 31 and 32are arranged in a housing 35 so that outer bearing races fit within theinside of housing 35 and inner bearing races fit on and rotate withshaft 50. A spacer 36 extends between an outer race of bearing 31 and acover plate 37 that is secured to housing 35. Cover plate 37 contains aseal 38 bearing against shaft 50 to keep dirt out of the inside ofhousing 35. Bore holes 39 in housing 35 form passageways to admitlubricating grease and provide pressure relief overflow.

A fan 40 is secured to shaft 50 above bearing housing 35 to directcooling air flow over housing 35 and cover plate 37, for removing heatfrom ball bearings 31 and 32 during operation. Above fan 40 is pulley51, which is preferably keyed to shaft 50 for transmitting drivingtorque from a motor-driven belt (not shown). Shaft 50 has supportbearings both above and below pulley 51.

Above pulley 51 and below discharge chute 18 is a bearing 60 that isbest shown in FIG. 5. A fixed support plate 59 holds a bearing mounthousing 61 in a fixed position surrounding shaft 50. Within housing 61is a ball bearing 62 having an inner race 63 fitted on and movable withshaft 50 and an outer race 69 that has a sliding fit allowing verticalmovement within mount 61. A seal 64 is arranged between housing 61 andshaft 50, and another seal 66 is arranged between cover plate 65 andshaft 50. Seals 64 and 66 help keep dirt from entering mount 61.

Shaft 50 moves a small amount vertically from thermal expansion andcontraction; and inner bearing race 63, while rotating with shaft 50,also moves axially with shaft 50 during thermal elongation. Outerbearing race 69 has a sliding fit within housing 61 that allows verticalmovement of outer race 69, even at elevated temperatures. An array ofcompression springs 68 arranged within mount 61 presses downward onouter race 69 to resist upward movement and prevent rotation of outerrace 69. Six compression springs equally spaced apart in a ring aroundshaft 50 are adequate for this purpose, and other spring arrangementscan also be used.

When shaft 50 elongates from thermal expansion and ball bearing 62 riseswith shaft 50, outer race 69 compresses springs 68 and rises along withinner race 63 to keep ball bearing 62 in working alignment. When shaft50 later cools and contracts, lowering ball bearing 62, springs 68extend somewhat and push outer race 69 downward in alignment with innerrace 63. A reasonably light pressure from springs 68 is adequate toprevent outer race 69 from rotating and keep outer race 69 in verticalalignment with inner race 63.

A fan 55 fixed to shaft 50 below bearing 60 directs cooling air overbearing 60 to remove heat from ball bearing 62. Fan 55 works in anopposite direction from fan 40.

The plate 59 that supports bearing 60 also supports a pipe 58 thatextends upward around shaft 50 into discharge passageway 18. At the topof pipe 58 is a bearing assembly 70 holding another ball bearing 75 forsupporting shaft 50, as shown in FIG. 6. A lower shaft seal 56 isarranged between a mount housing 71 and shaft 50, and an upper shaftseal 54 is arranged between a mount cover plate 73 and shaft 50. Anarray of compression springs 78 retained in cover plate 73 presses downagainst an outer race 74 of ball bearing 75. As previously described forbearing 60, springs 78 allow outer bearing race 74 to rise with innerbearing race 76 when shaft 50 elongates thermally. This is possiblebecause outer race 74 has a sliding fit within mount housing 71 againstthe resistance of springs 78.

The arrangement of bearing 75 and bearing mount 71 within dischargepassageway 18 subjects bearing 75 to the risk of pulverized material inchute 18 entering housing 71. To reduce this risk, plate 79 is fixed onshaft 50 above cover plate 73 for mount 71. Plate 79 spins with shaft 50and thereby throws pulverized material radially outward to divert suchmaterial away from bearing housing 71. This helps keep ball bearing 75clean.

Plate 79, being fixed to shaft 50, rises with shaft 50 when thermalelongation occurs. Rising of plate 79 opens a gap between the undersideof plate 79 and the top of housing cover 73. To inhibit entry ofpulverized material into such a gap, plate 79 has a ring 77 extendingdownward into a corresponding groove 67 formed in cover plate 73. Ring77 and groove 67 are concentric with shaft 50 so that ring 77 spinswithin groove 67 and provides a material barrier across a gap betweencover plate 73 and the underside of plate 79. These measures, inconjunction with shaft seals 71 and 72, assure that bearing 75 remainsclean. Many different configurations of rings and grooves can be usedfor such a purpose.

An upper bearing assembly 80 is arranged on a support plate 57 aboveprocessing chamber 12 at an upper region of shaft 50, as best shown inFIG. 7. Mount housing 86 of assembly 80 contains a pair of ball bearings81 and 82, each having a sliding vertical fit within housing 86. Anarray of compression springs 88 presses downward on the outer race ofbearing 82 so that both bearings 81 and 82 can rise with thermalelongation of shaft 50 against the pressure of springs 88. Shaft seals83 and 84 are arranged respectively in mount housing 86 and in housingcover plate 85. A fan 87 arranged above cover plate 85 directs coolingair over housing 86 for cooling bearings 81 and 82.

The bearing assemblies 60, 70, and 80, arranged above fixed lowerbearing 30, all have housing and spring arrangements that allow outerbearing races to rise with thermal elongation of shaft 50. This ensuresthat all bearings run in alignment and give proper support to shaft 50under operating conditions. Without such provisions for axial movementof bearings with shaft 50, bearings are destroyed as heat is generatedfrom the work done in processing chamber 12. Many different springarrangements and configurations of bearings and mount housings arepossible, providing the bearings are given freedom of vertical movement.

Within processing chamber 12, the throughflow of material beingpulverized has been improved and the aggressiveness of the pulverizingaction has been enhanced by several improvements. At an upper region ofprocessing chamber 12 is arranged a ring 52 that has a multi-sidedinside surface 53 that is beveled to face downward toward uppermostimpeller 15, as best shown in FIGS. 8-10. Downwardly beveled faces 53are wider at corners where faces meet, as shown in FIG. 9, and arenarrower in central face regions, as shown in FIG. 10. Ring 52 directsmaterial downward into contact with vanes 16 on uppermost impeller 15 sothat any material bouncing upward into contact with ring 52 is deflectedback downward to encounter pulverizing force.

Rings 20 that surround impellers 15 are also improved, as shown in FIGS.11-13. Rings 20 can have different numbers of inward facing surfaces 21,and these are preferably inclined inward from bottom to top, as shown inFIG. 10. A 10 degree inclination for ring surfaces 21 is preferred, butother angles of inclination may also work. The inward slope of surfaces21 makes their upper regions extend further into processing chamber 12than their lower regions, which tends to deflect material downward intoimpellers 15 and vanes 16. The inward inclination of surfaces 21 of asuccession of rings 20 enhances the throughflow of material beingpulverized and also helps direct pulverizable material into contact withvanes 16 of impellers 15.

Inward facing surfaces 21 of rings 20 are also preferably provided withridges and grooves, as shown in FIG. 13. Preferably evenly spaced ridges22 separated by grooves 23 provide a jagged or zigzag contour forsurfaces 21 for scattering material impacting on surfaces 21. Slopingsides 24 of ridges 23 deflect impacting material in various directions,depending on angle of incidence. Sloping ridge sides 24 can also lead todouble impacts of material glancing off of one ridge side and impactingagainst another. The result is to deflect or rebound material indifferent directions, adding randomness to the pulverizing process andmaking pulverization more aggressive.

In preferred embodiments of the present invention, modifications to thepulverizer described in the '044 patent and herein in connection withFIGS. 3-13 may be implemented as part of pulverizers 116 and 128. Forexample, rather than using a shaft that is mounted on floating bearings(as shown in FIGS. 3-7), the present invention may also be implementedwith a shaft that has a coupling between portions of the shaft betweenone or more stationary bearings or that is cooled to prevent expansion.More particularly for example, as shown in FIGS. 14A and 14B, shaft 50of the pulverizer of the '044 patent and FIGS. 3-13 may be split intotwo or more portions and connected by a torque transferring coupling 400or 402. As illustrated, coupling 400 is a spline shaft that connects thetwo halves of shaft 50 and coupling 402 is a compressible coupling thatconnects the two halves of shaft 50, however, any suitable type ofcoupling 400 could be used. As illustrated in FIG. 15, shaft 50 of thepulverizer of the '044 patent and FIGS. 3-13 could additionally oralternatively be cooled to prevent expansion. The approach shown uses acooling liquid 508 that is pumped through shaft 50 to keep it fromexpanding. Cooling liquid 508 may be stored in a reservoir 506, thenpumped by a pump 502 through a rotary coupler 510 into rotating shaft 50back out another rotary coupler 510 into a radiator or heat exchanger504 and back into reservoir 506.

Other examples of modifications that could be made to the pulverizer ofthe '044 patent and FIGS. 3-13 are shown in FIGS. 16 and 17. Asillustrated in FIG. 16, shaft 50 of the pulverizer could include athreaded section 602 and a pair of nuts 604 and 606 that enable a userto adjust the gaps 608 between vanes 16 of impellers 15 and bafflesplates 14. Gaps 608 are adjusted by turning nut 604 to adjust the heightof impeller 15 resting thereon. Once the height is set, nut 606 is madesnug against nut 604 to lock in the setting. Because the remainingimpellers 15 rest on the bottom impeller (and thus axially slide onshaft 50 while remaining rotationally fixed with respect to shaft 50),adjusting nut 604 causes all of the gaps 608 to be adjusted. By properlytuning gaps 608, the pulverizer can be made to operate most efficiently.The preferred gap spacing is about 0.062 inches for waste glass,although other gap spacings may be used with glass or other types ofmaterials.

Turning to FIG. 17, still another modification to the pulverizer of the'044 patent and FIGS. 3-13 is shown. As can be seen, this modificationincludes incorporating additional vanes 702 along the bottom of one ormore of impellers 15. Preferably, vanes 702 are only used on the bottomof the lowest impeller 15 in the pulverizer and vanes 702 are smallerthan vanes 16. Vanes 702 provide a restriction on the flow of thematerial being passed out of the pulverizer. This restriction thencauses the material to become further pulverized. Preferably, fifteenvanes 16 and three vanes 702 are used on the bottom impeller 15, fifteenvanes 16 and no vanes 702 are used on the middle impellers 15, andeighteen vanes 16 and no vanes 702 are used on the top impeller 15.Furthermore, preferably, the spacing 704 and 706 between the vanes 16and 702 and plates 14 are tuned identically to about 0.062 inches (e.g.,using the mechanism shown in FIG. 16), although any suitable spacing orcombination of spacings could alternatively be used.

Also shown in FIG. 17 are a variation of rings 20 of the pulverizer.Rather than being constructed with an inside radius that decreases frombottom to top (as can best be seen in FIG. 3), rings 708 shown in FIG.17 decrease in radius symmetrically from the middle height of the ringstoward both the bottom and the top of the rings. In this way, the ringscan be flipped over during maintenance of the pulverizer in order tocompensate for the wear that typically occurs at near the inside-top ofthe rings without rebuilding or replacing the rings.

In accordance with the present invention, fine particle materials, suchas those produced using system 100 of FIGS. 1A-1C, may be used toprovide pigment blends containing randomly geometrically shapedparticles suitable for use with one or more coloring agents such aspigments, metal flakes, coated mica, holographic flakes, colored orcoated microbeads, colored or coated glass chips and other similarcoloring agents. Alternatively, the coloring agents may be present in acolored base coating or substrate over which a transparent paint orcoating composition containing the pigment blends of this invention canbe applied. Most preferably, the fine particle chips are made of glass.

While the pigment blend may contain coated fine glass particle chipsthat have an opaque, mirrorized, and/or reflectorized coating, the glasschip mixture preferably includes glass chips that are transparent toallow light transmission. The transparent glass chips may includecolorless and/or colored glass chips.

If the fine glass particle chips are colored, they may be used eitheralone or in combination with other colored glass chips to providecoloration to the pigment blend. The colored glass chips may have thesame color as the coloring agents included in the pigment blend toenrich and deepen the apparent color of the other included coloringagents. Alternatively, the fine colored glass particles may have adifferent color to create secondary colors when viewed in combinationwith one or more coloring agents.

Because the fine colored glass particles may themselves act as acoloring agent, they may be used to replace pigments that aretraditionally added to pigment blends. Because the color in coloredglass are fused into the glass, colored glass chips may be a goodcoloring agent because the color will not leach out with time orexposure to various external elements such as high temperature andweather. Different colored glass chips may be mixed together to formsecondary colors when the colored glass chips are viewed in combination.Secondary colors created by mixing two different colored glasses mayalso be subsequently mixed with primary colors available in other typesof colored glass and/or other coloring agents to create apparenttertiary colors. Other color combinations necessary to achieve thedesired color through the use of colored glass and/or other coloringagents will be evident to those skilled in the art.

The fine glass particle materials may be formed from virgin or recycledglass. Recycled glass is preferred because of its very low cost andbecause it helps preserve the environment by conserving naturalresources and by reducing the amount of waste that must ultimately bestored in landfills. Recycled glass may be readily obtained from avariety of sources, such as a local recycling center, and may includeclear glass (e.g., from jars), green glass (e.g., from certain beerbottles), amber glass (e.g., from certain soda bottles and other beerbottles), and mirrored glass (e.g., from recycled automobiles, home andoffice construction waste, and architectural glass).

Because recycled glass often already contains additives such ascoloration or coatings that make the material colored, opaque,reflective, mirrorized, etc., the cost to produce useful pigment blendsfrom recycled glass is even more inexpensive than attempting to usevirgin glass to which coloration and/or coating must often be added.

The fine particle chips preferably are under 100 μm in the largestdimension. Because paint and coatings on substrates commonly are lessthan about 70 μm thick, the largest dimension of the chips musttypically be less than 70 μm so that the paint or coating containing thechips appears and feels smooth on the substrate. However, becauseindividual layers of the paint or coating on a substrate may be as thinas 20-30 μm, the chips preferably are smaller than 30 μm in the largestdimension. Particle sizes larger than 30 μm may be tolerated, however,if the particle lies flat in the paint or coating composition such thatthe particle height extends not more than a few microns above thesurface of the paint or coating on the substrate. Plastics, such asinjection molded plastics and the like, may have surfaces that arerougher in texture, and consequently may include glass chips with largerparticle size for visual and functional enhancing purposes withoutdegrading or detracting from the apparent smoothness of the article.Preferably, the chips should be no larger than 40 μm in thosecircumstances.

To ensure the paint or coating containing the fine particle chipsappears and feels smooth on a substrate while preserving the enhancedvisual effects that the chips provide, at least 95% of the chips mostpreferably are between 5 to 15 μm in the largest dimension. The chipswill typically contain a distribution of particle sizes. The leadingedge of the curve most preferably should not exceed 30 μm. The particlesize may be determined by a Malvern MasterSizer 2000, or any othersuitable particle size characterizer known to those skilled in the art.FIG. 19 illustrates a particle size distribution 1900 of particles madein accordance with the present invention and which are suitable for usein the pigment blend of the present invention. FIGS. 18A-18D showscanning-electron-microscope micrographs 1801-1804 of mirrorized glasschips produced in accordance with the present invention. FIGS. 18A-18Dillustrate the randomly geometric shapes suitable for use in the presentinvention.

Although the chips may be formed in using system 100, it should be notedthat the glass chips may also be formed by any other method, providedthat method produces random shaped particles having the aforementionedcharacteristics.

The glass chips may be made from any variety of glass compositionsincluding silica glass, quartz, soda lime glass, electroconductiveglass, sol-gel glass, organically modified sol-gel glass etc. The glassis preferably inorganic, inert, and does not react with other componentsof the pigment blend. Although the glass chips may be non-tempered, theypreferably are tempered to provide greater durability. Because temperedglass chips are tougher, they are more durable and are better able topreserve their geometric shape, which is important to obtaining enhancedvisual effects from the glass chips.

The transparent glass chips preferably have an index of refractionbetween 1.5 to 2.5, more preferably between 1.9 to 2.1, or mixturesthereof. The transparent glass chips preferably transmit light in theultraviolet (UV) spectrum (between 200 to 400 nm), visible spectrum(between 400 to 800 nm), infrared (IR) spectrum (between 800 nm to 10μm), or combinations thereof. More preferably, the transparent glasschips transmit visible and IR light while inhibiting UV transmission. Bylimiting UV transmission, the chips can reduce the damaging effect thatUV light may have on paint, a coating, and/or a substrate beneath theglass chips. Most preferably, the transparent glass chips transmits onlyvisible light. For specific applications, the glass chips may alsoselectively transmit and/or inhibit one or more wavelengths in one ormore of the aforementioned spectral regions.

The reflective fine particle chips may be optically opaque, mirrorized,or reflectorized, such that the reflective chips reflect or emit lightfrom the surface of the chips into and through the transparent glasschips present, or against coloring agents. These reflective chips incombination with one or more coloring agents give added depth andintensity to the visual appearance and color of the composition orsubstrate containing the pigment blend of this invention. The pigmentblends containing the reflectorized chips may contain suitableadditives, known to those skilled in the art, to create a variety ofcolors.

Alternatively, the reflective chips may be luminescent,electroluminescent, or phosphorescent. Each of those properties may beobtained by coating the chips with conventional luminescent,electroluminescent, or phosphorescent compositions known to thoseskilled in the art. Where necessary, the coating may also beelectroconductive.

The pigment blends containing the glass chips are suitable for use withmulti-layer paint systems, such as those used on automobiles. Automobilepaint systems typically comprise a base color coating having a 20 to 24micron thick film build and a 42 to 48 micron thick clear coat. Untilnow, pigment blends of the present invention could not be produced on acommercial scale and used without the difficulties of film protrusion orother undesirable appearance factors.

In another embodiment, pigment blends containing the glass chips may beused in a mono-layer coating (non-clear coat) for exterior and interiorpaint applications. The pigment blends of this invention add a verysatiny appearance to the surface while also creating a scatteredreflective and luminescent appearance.

In another embodiment, particulate solids, such as oyster shells, clamshells, rubber, rock minerals, coal, aluminum, etc., that have randomlygeometric shapes and sizes, may also be used for visual enhancementpurposes in pigment blends in accordance with the present invention.

The presence of particulate solids in pigment blends offers the addedadvantage of reducing the amount of volatile organic compounds thatcommonly are used in paint and coating compositions. In alternativeembodiments, lighter density particles may be used to reduce settlingproblems that can arise with heavier density particles.

Paint or coating compositions containing pigment blends of the presentinvention may be applied by any suitable method known to those skilledin the art, including calendering, spraying, brush painting, or anyother standard method of applying paint or coating compositions.

The pigment blends of the present invention may be used on a variety ofsubstrates, including metal, ceramic, glass, asbestos, human skin,leather, vinyl, plastic, polyester, epoxies, fabrics, wood, rubber,etc., for visual and functional enhancement. For example, a clearcoating for wood may be enhanced with a pigment blend containingcolorless glass chips and/or colored glass chips. The glass chips canincrease the visual dimensionality of the wood by enhancing the tone andexpanding the apparent definition of the ticking or grain in the wood,while also providing functional enhancement such as improved colortravel.

In addition, substrates containing the pigment blend of the presentinvention can show improved abrasion resistance, which may beparticularly useful in items such as articles of clothing, includingleather goods. Substrates containing pigment blends with the fineparticle can also show improved light fastness if the chips containsuitable UV screening. The fine particle chips may also be used as acomponent of a pigment blend in cosmetics to provide enhanced visual andfunctional properties. For example, cosmetics containing the fineparticle materials may be used to help provide UV screening for theskin, camouflage blemishes, cellulite, wrinkles, varicose veins or otherskin imperfections, and enhance the visual effect of the coloring agentscontained within the pigment blend of the cosmetics.

Surface visibility of articles may be improved with pigment blendscontaining mirrorized and/or reflectorized fine particle chips. Inparticular, pigment blends containing mirrorized glass chips providesuperior reflectivity and visibility compared to blends containing metalflakes. Such pigment blends can improve safety while also providing anaesthetically pleasing appearance. Because mirrorized or reflectorizedglass chips display scattered reflectivity, enhanced night and day timesurface visibility can be achieved from both multiangle light sourcesand light sources close to the viewing angle of an observer.

It will be understood that the foregoing is only illustrative of theprinciples of the invention, and that various modifications can be madeby those skilled in the art without departing from the scope and spiritof the invention, which is limited only by the claims that follow.

What is claimed is:
 1. A pigment blend comprising a plurality of glasschips having a substantially random geometrical shape and a particlesize less than about 100 microns; wherein said glass chips have areflective coating.
 2. A pigment blend comprising a plurality of glasschips having a substantially random geometrical shape and a particlesize less than about 100 microns; wherein said glass chips have anopaque coating.
 3. A pigment blend comprising a plurality of glass chipshaving a substantially random geometrical shape and a particle size lessthan about 100 microns; wherein said glass chips have anelectroconductive coating.
 4. The pigment blend according to any one ofclaims 1-3, wherein said particle size is less than about 30 micron. 5.The pigment blend according to any one of claims 1-3 wherein said glasschips are colorless, colored, luminescent, or phosphorescent.
 6. Thepigment blend according to any one of claims 1-3 further including acoloring agent, wherein said coloring agent is selected from the groupconsisting of glass chips, pigments, et al flakes, coated mica,holographic flakes, clam shells, oyster shells, and glass beads.
 7. Thepigment blend according to any one of claims 1-3, wherein said glasschips have an index of refraction between 1.5 to 2.5.
 8. The pigmentblend according to any one of claims 1-3, wherein said glass chipssubstantially inhibit transmission of light in the ultraviolet spectrum.9. The pigment blend according to claim 8, wherein said glass chipssubstantially inhibit transmission of light in the infrared spectrum.10. The pigment blend according to claim 5, wherein said luminescentglass chips are electroluminescent.